| M | Daniel MONFORT | 25/01/2006 | 10 Kilometres Race Walk | Final | 8 | 40:43 |
| M | Daniel MORILLA GARCIA | 14/09/2005 | 10 Kilometres Race Walk | Final | 14 | 41:07 |
| M | Miguel ESPINOSA OLIVARES | 30/01/2006 | 10 Kilometres Race Walk | Final | 12 | 40:55 |
| W | Griselda SERRET | 09/07/2005 | 10 Kilometres Race Walk | Final | 6 | 46:12 |
| W | Aldara MEILÁN | 02/10/2006 | 10 Kilometres Race Walk | Final | 2 | 45:12 |
| W | Sofia SANTACREU | 07/02/2006 | 10 Kilometres Race Walk | Final | 3 | 45:17 |
| W | Paula JUAREZ | 30/10/2000 | 20 Kilometres Race Walk | Final | 14 | 1:31:56 |
| W | Lucia REDONDO | 03/08/2003 | 20 Kilometres Race Walk | Final | 21 | 1:33:03 |
| W | Lidia SANCHEZ-PUEBLA | 17/07/1996 | 20 Kilometres Race Walk | Final | 8 | 1:30:24 |
| W | Antia CHAMOSA | 07/10/1999 | 20 Kilometres Race Walk | Final | 9 | 1:30:32 |
| M | Paul MCGRATH | 07/03/2002 | 20 Kilometres Race Walk | Final | 2 | 1:19:14 |
| M | Marc TUR | 30/11/1994 | 20 Kilometres Race Walk | Final | 29 | 1:22:27 |
| M | Álvaro LÓPEZ | 24/03/1999 | 20 Kilometres Race Walk | Final | 8 | 1:20:20 |
| M | Iván LÓPEZ | 29/03/1997 | 20 Kilometres Race Walk | Final | 28 | 1:22:18 |
| M | Diego GARCÍA CARRERA | 19/01/1996 | 20 Kilometres Race Walk | Final | 3 | 1:19:51 |
| X | Spain | | Marathon Race Walk Mixed Relay | Final | 3 | 2:57:47 |
| X | Spain 2 | | Marathon Race Walk Mixed Relay | Final | 7 | 3:00:37 |
| X | Spain 3 | | Marathon Race Walk Mixed Relay | Final | 10 | 3:02:43 |