| Sex | Athlete | DOB | Discipline | Round | POS | Mark |
|---|---|---|---|---|---|---|
| W | Veronika TKACHUK | 03/08/2008 | 10 Kilometres Race Walk | Final | 12 | 49:14 |
| M | Serhii SVITLYCHNYI | 13/07/1994 | Half Marathon Race Walk | Final | 25 | 1:31:46 |
| M | Ihor HLAVAN | 25/09/1990 | Half Marathon Race Walk | Final | 74 | |
| M | Mukola RUSHCHAK | 30/10/2003 | Half Marathon Race Walk | Final | 34 | 1:34:17 |
| W | Mariia SAKHARUK | 14/10/1995 | Half Marathon Race Walk | Final | 10 | 1:38:15 |
| W | Hanna SHEVCHUK | 18/07/1996 | Half Marathon Race Walk | Final | 7 | 1:37:39 |
| W | Lyudmila OLYANOVSKA | 20/02/1993 | Half Marathon Race Walk | Final | 8 | 1:37:54 |