| Sex | Athlete | DOB | Discipline | Round | POS | Mark |
|---|---|---|---|---|---|---|
| M | Eduard MURAVSKYI | 28/07/2006 | 10 Kilometres Race Walk | Final | 38 | 44:19 |
| W | Hanna SHEVCHUK | 18/07/1996 | 20 Kilometres Race Walk | Final | 15 | 1:32:04 |
| M | Mukola RUSHCHAK | 30/10/2003 | 20 Kilometres Race Walk | Final | 34 | 1:23:17 |
| X | Ukraine 2 | Marathon Race Walk Mixed Relay | Final | 22 | 3:05:55 |